This dataset contains daily and sub-daily hydrometeorological and soil observations from COSMOS-UK (cosmic-ray soil moisture monitoring network) from the start of the network, in October 2013, to the end of 2015. These data are from 32 sites active across Great Britain during this time, recording a range of hydrometeorological and soil variables. Each site in the network hosts a cosmic-ray sensing probe; a novel sensor technology which can be used, in combination with hydrometeorological data, to calculate the volumetric water content of soil over a field scale. The hydrometeorological and soil data are recorded at a 30 minute resolution and they include neutron counts from the Cosmic-ray sensing probe, humidity and atmospheric pressure data that are used to derive volumetric water content at two temporal resolutions (hourly and daily). Also included are soil heat flux, air temperature, wind speed and net radiation data which are used to derive potential evapotranspiration at a daily resolution.